{"id":104,"date":"2021-10-02T23:37:32","date_gmt":"2021-10-02T23:37:32","guid":{"rendered":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/?post_type=part&#038;p=104"},"modified":"2022-01-10T19:23:24","modified_gmt":"2022-01-10T19:23:24","slug":"flux-equations","status":"publish","type":"part","link":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/part\/flux-equations\/","title":{"raw":"5  Flux Equations","rendered":"5  Flux Equations"},"content":{"raw":"<div class=\"flux-equations\">\r\n<p class=\"import-Normal\">With <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/effect-of-solid-particles-embedded-in-the-gas\/#equation_14\">Equation 14<\/a> now understood in the context of conservation of momentum, we replace partial pressure, <em class=\"import-Eqinline\">p<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub>, with the more familiar molar concentration, <em class=\"import-Eqinline\">C<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub> and use <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/fluxes-that-comprise-total-diffusion-flux\/#equation_10\">Equation 10<\/a> to replace <em class=\"import-Eqinline\">J<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub> and obtain Equation 22.<a id=\"equation_22\"><\/a><\/p>\r\n\r\n<table style=\"border: none; border-collapse: collapse; width: 100%;\">\r\n<tbody>\r\n<tr>\r\n<td style=\"width: 10%;\"><\/td>\r\n<td style=\"width: 80%; text-align: center;\">[latex]\\displaystyle -D\\frac{dC_{A}}{dl}=\\left ( x_{B}N_{A}^{D}-x_{A}N_{B}^{D} \\right )+\\frac{D}{D_{A}^{K}}N_{A}^{D}[\/latex]<\/td>\r\n<td style=\"width: 10%; text-align: right;\">(22)<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n<p class=\"import-Normal\">Equation 22 and the corresponding equation for species <em class=\"import-Eqinline\">B<\/em> (interchange the subscripts) apply in both the molecular and transition regimes under both isobaric and non-isobaric conditions. The total diffusive fluxes are expressed by Equations <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/grahams-law\/#equation_20\">20<\/a> and <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/grahams-law\/#equation_21\">21<\/a> for the non-isobaric and isobaric condition, respectively.<\/p>\r\n\r\n<\/div>","rendered":"<div class=\"flux-equations\">\n<p class=\"import-Normal\">With <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/effect-of-solid-particles-embedded-in-the-gas\/#equation_14\">Equation 14<\/a> now understood in the context of conservation of momentum, we replace partial pressure, <em class=\"import-Eqinline\">p<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub>, with the more familiar molar concentration, <em class=\"import-Eqinline\">C<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub> and use <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/fluxes-that-comprise-total-diffusion-flux\/#equation_10\">Equation 10<\/a> to replace <em class=\"import-Eqinline\">J<\/em><sub class=\"import-Eqinline\"><em>A<\/em><\/sub> and obtain Equation 22.<a id=\"equation_22\"><\/a><\/p>\n<table style=\"border: none; border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 10%;\"><\/td>\n<td style=\"width: 80%; text-align: center;\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-content\/ql-cache\/quicklatex.com-ec6548b8e61fe50c79f161c87e49aa84_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#100;&#105;&#115;&#112;&#108;&#97;&#121;&#115;&#116;&#121;&#108;&#101;&#32;&#45;&#68;&#92;&#102;&#114;&#97;&#99;&#123;&#100;&#67;&#95;&#123;&#65;&#125;&#125;&#123;&#100;&#108;&#125;&#61;&#92;&#108;&#101;&#102;&#116;&#32;&#40;&#32;&#120;&#95;&#123;&#66;&#125;&#78;&#95;&#123;&#65;&#125;&#94;&#123;&#68;&#125;&#45;&#120;&#95;&#123;&#65;&#125;&#78;&#95;&#123;&#66;&#125;&#94;&#123;&#68;&#125;&#32;&#92;&#114;&#105;&#103;&#104;&#116;&#32;&#41;&#43;&#92;&#102;&#114;&#97;&#99;&#123;&#68;&#125;&#123;&#68;&#95;&#123;&#65;&#125;&#94;&#123;&#75;&#125;&#125;&#78;&#95;&#123;&#65;&#125;&#94;&#123;&#68;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"40\" width=\"290\" style=\"vertical-align: -17px;\" \/><\/td>\n<td style=\"width: 10%; text-align: right;\">(22)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p class=\"import-Normal\">Equation 22 and the corresponding equation for species <em class=\"import-Eqinline\">B<\/em> (interchange the subscripts) apply in both the molecular and transition regimes under both isobaric and non-isobaric conditions. The total diffusive fluxes are expressed by Equations <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/grahams-law\/#equation_20\">20<\/a> and <a href=\"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/chapter\/grahams-law\/#equation_21\">21<\/a> for the non-isobaric and isobaric condition, respectively.<\/p>\n<\/div>\n","protected":false},"parent":0,"menu_order":5,"template":"","meta":{"pb_part_invisible":false,"pb_part_invisible_string":""},"contributor":[],"license":[],"class_list":["post-104","part","type-part","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/pressbooks\/v2\/parts\/104","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/pressbooks\/v2\/parts"}],"about":[{"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/wp\/v2\/types\/part"}],"version-history":[{"count":7,"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/pressbooks\/v2\/parts\/104\/revisions"}],"predecessor-version":[{"id":400,"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/pressbooks\/v2\/parts\/104\/revisions\/400"}],"wp:attachment":[{"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/wp\/v2\/media?parent=104"}],"wp:term":[{"taxonomy":"contributor","embeddable":true,"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/wp\/v2\/contributor?post=104"},{"taxonomy":"license","embeddable":true,"href":"https:\/\/books.gw-project.org\/flux-equations-for-gas-diffusion-in-porous-media\/wp-json\/wp\/v2\/license?post=104"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}