Table 4 - Commonly applied methods for removal of fluoride from drinking water (after Heidweiller, 1990; Jagtap et al., 2012; Mohapatra et al., 2009; Sandoval et al., 2021; Van der Bruggen et al., 2008).

Treatment method Capacity/dose Working pH Interferences Advantages Disadvantages Relative cost
Coagulation
Alum (aluminium sulphate) 150 mg/mg F Non-specific - Established process Sludge produced, treated water is acidic, residual Al present, may have adverse taste Medium-high
Lime 30 mg/mg F Non-specific - Established process Sludge produced, treated water is alkaline, may have adverse taste Medium-high
Alum + lime (Nalgonda) 150 mg alum + 7mg lime/mg F Non-specific, optimum 6.5 - Low-tech, established Sludge produced, high chemical dose, residual Al present, may have adverse taste Medium-high
Gypsum + fluorite 5 mg gypsum + < 2 mg SO4 /mg F Non-specific - Simple Needs trained operators, low efficiency, high residual Ca, SO4 Low-medium
Calcium chloride 3 mg CaCl2/mg F 6.5-8.0 - Simple Needs additional flocculent (e.g., FeCl3) Medium-high
Electrochemical
Electrocoagulation High 6.0-8.0 Sulphate, phosphate, bicarbonate Few chemicals Needs electrode replacements, power; passivated film formation, potential residual Al in treated water Medium-high
Adsorption/ion exchange
Activated carbon Variable < 3 Many - Large pH changes before and after treatment High
Plant carbon 300 mg F/kg 7 - Locally available Requires soaking in potassium hydroxide Low-medium
Zeolites 100 mg F/kg Non-specific - - Poor capacity High
Defluoron 2 360 g F/m3 Non-specific Alkalinity - Disposal of chemicals used in resin generation, Cl in treated water Medium
Clay pots 80 mg F/kg Non-specific - Locally available Low capacity, slow Medium
Activated alumina 1200 g F/m3 5.5 Alkalinity Effective, well-established Needs trained operators, chemicals not always available Medium
Bone 900 g F/m3 > 7 Arsenic Locally available May give taste, degenerates, not universally accepted Low
Bone char 1000 g F/m3 > 7 Arsenic Locally available, high capacity Not universally accepted, may give adverse color, taste Low
Membrane techniques
Electrodialysis High Non-specific - Can remove other ions, used for high salinity, no chemicals Skilled operators, high cost, membrane fouling Very high
Reverse osmosis High Non-specific - Can remove other ions, used for high salinity, no chemicals Skilled operators, high cost, membrane fouling, can remove beneficial solutes, residual saline wastewater Very high
Nanofiltration High Non-specific - Can remove other ions, no chemicals Skilled operators, high cost, membrane fouling, can remove beneficial solutes, residual saline wastewater Very high